Twenty years ago, says Gudberg, Icelandic teens were among the heaviest-drinking youths in Europe. A couple of minutes ago, we passed two halls dedicated to badminton and ping pong. Or they might be on outings with their parents.
Sign in. Actress The Hunger Games. She has a twin sister, actress Autumn Shieldsand an older brother, actor River Shields.
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Donald Scavia receives funding from government agencies and foundations in support of his research. Republish our articles for free, online or in print, under Creative Commons licence. Over the past two decadesscientists have developed ways to predict how ecosystems will react to changing environmental conditions.
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A systematic comparison of empty tetralactam macrocycles containing 1,3-benzenedicarboxamide, 2,6-pyridinedicarboxamide, and 1,3-adamantanedicarboxamide bridging units finds that macrocycles with adamantyl bridging units exhibit weaker non-covalent affinity for an encapsulated guest. In the case of interlocked squaraine rotaxanes with macrocycles containing phenylene sidewalls, the structural change induced by the adamantyl bridging units produces a more loosely held rotaxane co-conformation that diminishes the ability of the surrounding macrocycle to protect the encapsulated squaraine dye from attack by nucleophiles. In the case of squaraine rotaxanes with macrocycles containing anthracene sidewalls, there is no obvious change in rotaxane co-conformation. But there is a difference with the corresponding squaraine rotaxane endoperoxide, namely a significantly slower rate of cycloreversion and oxygen release.